Polar stacking of molecules in liquid chloroform.

نویسندگان

  • J J Shephard
  • A K Soper
  • S K Callear
  • S Imberti
  • J S O Evans
  • C G Salzmann
چکیده

Using neutron diffraction and the isotopic substitution technique we have investigated the local structure of liquid chloroform. A strong tendency for polar stacking of molecules with collinear alignment of dipole moments is found. We speculate that these polar stacks contribute to the performance of chloroform as a solvent.

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عنوان ژورنال:
  • Chemical communications

دوره 51 23  شماره 

صفحات  -

تاریخ انتشار 2015